No, only one per account, if it were 2 accounts then yes, but the PC version doesn't allow for multiple profiles on one account. Best you could do would be to transfer as value much as possible from that account to your via fleet carrier or other method and buy a second account for PC. Trying to transfer 2 profiles from an Xbox account to PC would require FDEV to give you 2 free Horizons accounts, and they aren't going to do that I suspect.