Head tracking is different from static screen or VR use in one fundamental way- when using head tracking, in order to see the screen in a stable manner, you often have to move your eyes in the opposite direction to the one in which you move your head.. this is a particularly unnatural motion, and can be uncomfortable, or even induce headaches/motion sickness. I am not surprised that you find it strange, OP- because it is!
There's not really anything definite to do, I certainly won't make stupid suggestions like taking drugs to play. However, the standard advice is give it time, try to adjust. Play for short periods only, and stop the very second that you feel uncomfortable, This allows you to build up tolerance. It's vital not to try to "push through" the discomfort, or you will set up bad associations through conditioning- making you automatically associate feeling unwell with using the head tracking, which is the opposite of what you want.
So.. to recap.. try sticking with it. Play for short bursts. If you feel strange, STOP. Get up, move away from the computer, maybe look out of the window/go for a walk. See if it gets better after building up a tolerance. Good luck.