help with 'open codex'?

I have open codex bound to: L ALT C.
Codex doesn't open. Tried combat and analysis mode.
Have to go to RUI and select codex to see it.

What am I missing?
 
Odd.
Could try binding it to just one character see if that changes the results.
I see the default binding O come up just after i scan something to show its related entry. so maybe the shortcut is dependent on a type of action.
 
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