Wrong Steam account linked...

So I purchased my second account via Steam, but some time ago apperantly I went ahead and linked my main Frontier account to my Steam account. Because I haven't read the EULA or warnings on Steam.
Now my main account already has LifeTime expension pass, and I want to purchase my second account Odyssey through steam. So I want to link my other Frontier account to my steam account. But I have questions and doubts...

I have couple of question, What will happen to my other frontier game purchases on steam, I have Jurrasic World & planet coaster? Will my Elite Dangerous account(s) reset if unlinked via ticket?
If I purchase Odyssey on Steam without getting my account unlinked, will I still get a CD-Key and add that to my second account? Currently when I log into my main account at frontier store I see that my steam is linked there. And CD-keys on Steam and frontier doesn't match. Since I originally bought my second account via steam.
And yes I know I need to contact support to get it unlinked. I just want to get some info about the process before starting it.
 
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