From my experience XMP profiles are not enabled in the BIOS by default, so buying faster more expensive RAM is a waste of money if you don't check and set your RAM to its fastest speed.
I recommend using CPU Z - select the Memory tab to check what speed and timings are applied to your RAM.
Next, check the SPD tab and select the appropriate Memory Slot number ( 1 to 4) that you have RAM installed in - if the details under the SPD tab are blank, select another memory slot until you get some setting data.
Have a look at the details in the Timing section. It should provide information on what frequency and settings are available for the particular RAM you have installed - mine has 4 timing tables, including 2 XMP tables.
You can easily determine which XMP profiles can be used for your RAM - and apply this setting in your BIOS.
Also note that some preset XMP profiles can be unstable and it is sometimes better to manually configure the RAM frequency and timings in the BIOS, as per the XMP table.
Once you have setup your RAM, I suggest using a testing or benchmarking program to test for any stability issues - I use a program called RealBench which can be downloaded from the ASUS website (Version 2.4. is the latest).
Running the RealBench "Stress Test" will check CPU and RAM by running a suite of tests that load up your system - it doesn't matter if you have another brand of motherboard, it will work fine. I like RealBench because it uses real applications and does not unnecessarily load your system to the extreme, but will quickly identify if your system is not stable at its current settings.
Hope this helps.