Exploration: if in doubt, it's not an Earth like world. 
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Take A Break
This cannot be said enough times - log out to the menu, stand up, walk around. Get some water, look out your window.
Elite is an amazing game, and it comes with it's own temporal distortion built in - you'll look at the clock, it will be 7:30. You'll look again after a couple jumps, and it will be 9:45.
It's just plain healthy to take little breaks from time to time. You won't miss anything. The galaxy has been here for 13.21 billion years. It will still be here in ten minutes.
KGB FOAM is good rule of thumb. Soviet secret service and some comfy Foam
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All players are hostile until proven other vice. Any one can be your enemy.
Always H-wake (jump to other star system not in system travel) away from players when you want to run away.
Holo triangle means other players has deployed hardpoints or has tried to fire something that is mapped to fire group (like FSDI)
Never let players behind you while in sc, if you are closer to stellar body than him (if you are closer you are slower (gravity effect plah plah) and he will catch up with you and interdict you). Always either face players or be faster than them in sc, and all ships have same accelerator in sc.