The first error looks like a badly formatted AppConfig.xml file.
The second error is not being able to write or create a database.
I suggest browsing to %LOCALAPPDATA% in windows explorer, then rename the existing CaptainsLog folder, and running/configuring CL. This will start with a clean setup. You can then move your existing DB files from the old folder to the new one.
Regards
p.s. Broken collar bone >.< I've had that 3 times now, twice when I was much younger and once a few years ago in Japan when I was snowboarding. All 3 times the same bloomin' left collarbone.
Ouch. >.<
It's back playing nice again, thanks Genar. Moved back my backed-up databases from Distant Worlds and it's all loaded correctly.
Both of mine have been cycling related, one training (2012) and one racing (last month) and both have involved surgery/metalwork!