I did. PS5 quality mode is very nice in solo for me, 60FPS and general graphics look sharper. On the other hand, the UI becomes fuzzy and quite unclear at times, compared to the PS4 version I used to play.
In private group, I went with a friend to the Guardian ruins to get his mats for the FSD, and when the skimmers got out and we started shooting at them, I got some pretty ugly frame drops in quality mode, so there's that. Basically, what you have in PS5 quality mode is nothing but the PS4 Pro version in BC.
The only really good thing is loading times are super fast now, system map with many bodies in it is opened faster, plotting route on galaxy map is also very fast now. But for the powerhouse PS5 is, it's not nearly enough.